In this first shot you can even make out the shape of the shuttle and which end is the pointy end, despite the blooming reflection of the setting sun.

In this next shot you can see that the orbiter has turned a bit as the nose is swinging from right to left.

This last shot was taken as the orbiter was almost out of site with the shuttle completely turned around and a green flash which I think is possibly the planned engine burn that will put the shuttle into a 150 mile high orbit.

Pretty cool huh?
-Steve